长江流域典型水源水库春季2-甲基异莰醇浓度及其影响因素
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1.南京师范大学;2.中国科学院南京地理与湖泊研究所;3.浙江省杭州生态环境监测中心

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国家自然科学(No.42271080, U2340209);中国科学院南京地理与湖泊研究所自主部署科研项目(NIGLAS2022GS03)


Occurrence of 2-methylisoborneol in typical drinking-water source reservoirs located in Changjiang River catchment in later spring
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Nanjing Institute of Geography and Limnology, Chinese Acedemy of Sciences

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    摘要:

    春末夏初是长江流域水源水库水质异味问题的高发期,但关于该区域水库异味物质发生的特征及影响因子尚不明晰。基于2024年5月调查的长江流域上、中、下游不同省份9座典型水源水库坝前区域水体2-甲基异莰醇(2-MIB)等异味物质含量状况及其环境条件,分析了影响该区域水源水库春季异味物质浓度高低的生态环境因子。结果发现,2-MIB是长江流域水源水库春季最常见的超标异味物质,9座水库坝前水柱2-MIB浓度均值为35.5 ng/L,超过生活饮用水卫生标准中该物质控制浓度阈值(10.0 ng/L)的样品数占比为59.4 %;相比而言,土臭素(GSM)均值仅为2.9 ng/L,超过生活饮用水卫生标准中该物质控制浓度阈值(10.0 ng/L)的样品数占例仅为12.5 %;异味物质β-环柠檬醛的均值为18.2 ng/L,β-环紫罗兰酮的均值为7.2 ng/L,引起饮用水异味的风险不大;2-MIB的源解析表明,假鱼腥藻(Pseudanabaena sp)可能该区域水源水库2-MIB的主要来源,其细胞密度与2-MIB浓度显著正相关(P<0.001);但也存在部分水库检测到2-MIB却未检出假鱼腥藻的现象,反映出2-MIB来源的复杂性。水体富营养化会显著提高2-MIB异味问题风险,2-MIB浓度与水体营养状态指数正相关。调查前一周内的累积降雨量(RF7)与2-MIB浓度负相关,说明短期强降雨等气象条件变化也会显著影响水库2-MIB浓度。研究表明,长江流域的水源水库尽管大都处于中营养水平,普遍面临2-MIB超标等阶段性水质异味风险。加强外源营养盐入库负荷的控制,优化库体食物链结构,进一步降低水库营养状态,有助于提升水库型水源地的供水质量。

    Abstract:

    There is highly risk of odorous compounds trouble in drinking water source reservoirs in the Changjiang River catchment in later spring. However, the key drivers for the odorous compound occurrence are remain unclear. During May 2024, we investigated nine drinking water source reservoirs across the upper, middle and lower reaches of the Changjiang River, measuring four odorous compounds, included 2-methylisoborneol (2-MIB), geosmin (GSM), β-cyclocitral (CYC) and β-ionone (ION), along with associated environmental factors. Results showed that 2-MIB was the most common odorous compound, with an average concentration of 35.5 ng/L across the 32 samples from 9 reservoirs (59.4 % exceeding the detection threshold of 10.0 ng/L). In contrast, GSM posed a lower risk, with an average concentration of 2.9 ng/L and only 12.5 % exceeding the threshold value of 10 ng/L, while CYC (averaged at 18.2 ng/L) and ION (averaged at 7.2 ng/L) exhibited minimal odorous concerns. Pseudanabaena sp. was identified as a likely major producer of 2-MIB, with its cell density showing a significant positive correlation with the concentration of 2-MIB. However, the presence of 2-MIB in two reservoirs without detectable Pseudanabaena suggests more complex 2-MIB sources in some reservoirs. Furthermore, 2-MIB levels were also positively related to the trophic state index (TSI), indicating that eutrophication could promoted 2-MIB production. Rainfall amount in 7 days ahead the sampling (RF7) was negative relative to 2-MIB concentration, suggested that short-term weather condition also influence the odorous situation in reservoirs. Despite generally mesotrophic conditions, the widespread 2-MIB exceedances highlight a persistent risk in these reservoirs. To ensure drinking water quality, measures such as reducing external nutrient loads and optimizing aquatic food webs are recommended.

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  • 收稿日期:2025-01-31
  • 最后修改日期:2025-04-10
  • 录用日期:2025-05-12
  • 在线发布日期: 2025-07-15
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