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引用本文:王子健,王毅.用生物模拟采样技术模拟研究不同取代氯酚在金鱼(Crassius auratus)体内的富集和降解.湖泊科学,2002,14(1):72-76. DOI:10.18307/2002.0111
WANG Zijian,WANG Yi.Bioaccumulation and Biodegradation of Cholorophenols in Semi-permeable Membrane Biomimetic Sampling Device and in Golden Fish (Crassius auratus). J. Lake Sci.2002,14(1):72-76. DOI:10.18307/2002.0111
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用生物模拟采样技术模拟研究不同取代氯酚在金鱼(Crassius auratus)体内的富集和降解
王子健, 王毅
中国科学院生态环境研究中心环境水化学国家重点实验室, 北京 100085
摘要:
在实验室控制条件的流动体系中,研究了九种典型氯酚类化合物在半渗透膜生物模拟采样器件 (SPMD)和金鱼体内的富集动力学过程.基于氯酚污染物在SPMD中的生物浓缩和在鱼体脂肪中生物富集的差别,研究了氯酚污染物在生物体内的降解性和降解作用的结构/效应关系.结果表明氯酚类污染物在SPMD中的浓缩作用和在鱼体中的富集作用非常相似.氯酚化合物的生物降解性随氯取代基数量增加而降低,并与氯取代基的位置有关.
关键词:  生物模拟技术  生物降解  氯酚  金鱼
DOI:10.18307/2002.0111
分类号:
基金项目:国家自然科学基金(40071073);中国科学院方向项目(KZCX2-410)
Bioaccumulation and Biodegradation of Cholorophenols in Semi-permeable Membrane Biomimetic Sampling Device and in Golden Fish (Crassius auratus)
WANG Zijian, WANG Yi
SKLEAC, Research Center for Eco Environmental Sciences, Beijing 100085, P.R.China
Abstract:
Bioaccumulation kinetics of 9 cholorophenols in semi-permeable membrane biomimetic sampling device and in fish was studied under controlled laboratory flowing-through conditions.Based on the difference between bioconcentration process in SPMD and bioaccumulation process of chlorophenols in fish the degradation and the structure/effects relationship of degradation of chlorophenols in fish was examined.The results showed that the chlorophenols under testing could be concentrated by SPMD in a similar way as it was concentrated by fish lipid.The biodegradability of chlorophenols decreased with increase of substitutions of chlorine atoms and is closely related to the position of chlorine substitution in the ring of benzene.
Key words:  Biomimetic sampling  biodeg radation  cholorophenols  Golden fish
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